Temperature-decoupled hydrogen sensing with Pi-shifted fiber Bragg gratings and a partial palladium coating.

A novel, to the best of our knowledge, sensor architecture for palladium-coated fiber Bragg gratings is proposed and demonstrated that allows highly accurate multi-parameter sensing and decoupling of hydrogen concentration from temperature. By means of partly Pd-coated Pi-shifted FBGs (PSFBGs), the notch wavelength of the narrow transmission band and the flank wavelength of the broader reflection band experience different hydrogen and temperature sensitivities. PSFBGs were calibrated at hydrogen concentrations between 800 and 10,000 ppm and temperatures from 20 to 40°C, and a decreased hydrogen sensitivity at increased temperatures was found. Nonlinear temperature-dependent hydrogen calibration functions were therefore determined. An iterative matrix algorithm was used to decouple hydrogen concentration and temperature and to account for the nonlinear calibration functions. Achieved improvements and results have great importance for real field applications of FBG-based hydrogen sensing.

Generalized and wavelength-dependent temperature calibration function for multipoint regenerated fiber Bragg grating sensors.

A new calibration methodology for regenerated fiber Bragg grating (RFBG) temperature sensors up to 700 °C is proposed and demonstrated. A generalized, wavelength-dependent temperature calibration function is experimentally determined that describes the temperature-induced wavelength shifts for all RFBG sensor elements that are manufactured with the same fabrication parameters in the wavelength range from 1465 nm to 1605 nm. Using this generalized calibration function for absolute temperature measurements, each RFBG sensor element only needs to be calibrated at one reference temperature, representing a considerable simplification of the conventional calibration procedure. The new calibration methodology was validated with 7 RFBGs, and uncertainties were found to be compliant with those of Class 1 thermocouples (< ±1.5 K or < ±0.4% of the measured temperature). The proposed calibration technique overcomes difficulties with the calibration of spatially extended multipoint RFBG sensor arrays, where setting up an adequate calibration facility for large sensor fibers is challenging and costly. We assume that this calibration method can also be adapted to other types of FBG temperature sensors besides RFBGs. An accurate and practical calibration approach is essential for the acceptance and dissemination of the fiber-optic multipoint temperature sensing technology.

Temperature and external strain sensing with metal-embedded optical fiber sensors for structural health monitoring.

An optical fiber with both temperature and strain fiber Bragg grating sensors were embedded into an aluminum cast structure during the casting process. Temperature and strain calibrations were carried out respectively for the metal-embedded sensors. Temperature and external strain decoupling was further demonstrated in a temperature range from 25 to 80 °C and an external strain range from 0 to ∼110 µÉ›. With the interpolated temperature measured by two temperature sensors at different positions, the external strain could be decoupled from temperature and thermal strain at the strain sensor. The temperature and external strain values obtained from our embedded optical fiber sensors agreed well with reference values, revealing the good performance of the metal-embedded optical fiber sensors. The difference between the measured values and the reference values are within ±5 µÉ› for external strain and ±1 °C for temperature. With only a single fiber, the in-situ temperature and external strain information in the aluminum structure can be monitored in real time, representing an important step towards fiber-optic smart casts. Our investigation demonstrates that embedded optical fiber sensors can be a promising method for structural health monitoring of metallic structures.

Fiber Bragg Sensors Embedded in Cast Aluminum Parts: Axial Strain and Temperature Response.

In this study, the response of fiber Bragg gratings (FBGs) embedded in cast aluminum parts under thermal and mechanical load were investigated. Several types of FBGs in different types of fibers were used in order to verify general applicability. To monitor a temperature-induced strain, an embedded regenerated FBG (RFBG) in a cast part was placed in a climatic chamber and heated up to 120 ∘C within several cycles. The results show good agreement with a theoretical model, which consists of a shrink-fit model and temperature-dependent material parameters. Several cast parts with different types of FBGs were machined into tensile test specimens and tensile tests were executed. For the tensile tests, a cyclic procedure was chosen, which allowed us to distinguish between the elastic and plastic deformation of the specimen. An analytical model, which described the elastic part of the tensile test, was introduced and showed good agreement with the measurements. Embedded FBGs - integrated during the casting process - showed under all mechanical and thermal load conditions no hysteresis, a reproducible sensor response, and a high reliable operation, which is very important to create metallic smart structures and packaged fiber optic sensors for harsh environments.

Early Detection of Cartilage Degeneration: A Comparison of Histology, Fiber Bragg Grating-Based Micro-Indentation, and Atomic Force Microscopy-Based Nano-Indentation.

We have determined the sensitivity and detection limit of a new fiber Bragg grating (FBG)-based optoelectronic micro-indenter for biomechanical testing of cartilage and compared the results to indentation-type atomic force microscopy (IT-AFM) and histological staining. As test samples, we used bovine articular cartilage, which was enzymatically degraded ex vivo for five minutes using different concentrations of collagenase (5, 50, 100 and 500 µg/mL) to mimic moderate extracellular matrix deterioration seen in early-stage osteoarthritis (OA). Picrosirius Red staining and polarization microscopy demonstrated gradual, concentration-dependent disorganization of the collagen fibrillar network in the superficial zone of the explants. Osteoarthritis Research Society International (OARSI) grading of histopathological changes did not discriminate between undigested and enzymatically degraded explants. IT-AFM was the most sensitive method for detecting minute changes in cartilage biomechanics induced by the lowest collagenase concentration, however, it did not distinguish different levels of cartilage degeneration for collagenase concentrations higher than 5 µg/mL. The FBG micro-indenter provided a better and more precise assessment of the level of cartilage degeneration than the OARSI histological grading system but it was less sensitive at detecting mechanical changes than IT-AFM. The FBG-sensor allowed us to observe differences in cartilage biomechanics for collagenase concentrations of 100 and 500 µg/mL. Our results confirm that the FBG sensor is capable of detecting small changes in articular cartilage stiffness, which may be associated with initial cartilage degeneration caused by early OA.

Transition from purely elastic to viscoelastic behavior of silica optical fibers at high temperatures characterized using regenerated Bragg gratings.

In this study, the response of regenerated fiber Bragg gratings (RFGBs) to axial forces was investigated in a temperature range from room temperature to 900 °C. For the first time, the transition from pure elastic to viscoelastic behavior around 700 °C of a standard SMF28 optical fiber was measured with an inscribed RFBG. An elastic model with linear temperature dependencies of Young's modulus and Poisson's ratio was established, and showed good agreement with the measurements up to temperatures of ∼500 °C. In the temperature range up to 900 °C, the RFBG response could be well described with a simple, single-material approach and a Burgers model that consists of a Kelvin and a Maxwell part. Based on the elastic parameter of the Maxwell part, the temperature-dependent force sensitivity of the RFBG was determined, and it showed a linear decrease in the range from room temperature to ∼500 °C, constant values in the range between ∼500 °C and ∼600 °C, and a strong increase at higher temperatures. While fulfilling the condition to operate in the elastic domain of the silica fiber, the investigations demonstrate that RFBGs can be used as force sensors up to temperatures of ∼600 °C - the range in which temperature-dependent force sensitivities have to be considered. The temperature-dependent parameters of the effective single-material model (elastic and viscoelastic part) are essential to describe the effective mechanical behavior of the optical fiber at high temperatures.

Fiber-Optic Multipoint Sensor System with Low Drift for the Long-Term Monitoring of High-Temperature Distributions in Chemical Reactors.

A low-drift fiber-optic sensor system, consisting of 24 regenerated fiber Bragg gratings (RFBG), equally distributed over a length of 2.3 m, is presented here. The sensor system can monitor spatially extended temperature profiles with a time resolution of 1 Hz at temperatures of up to 500 °C. The system is intended to be used in chemical reactors for both the control of the production ramp-up, where a fast time response is needed, as well as for production surveillance, where low sensor drifts over several years are required. The fiber-optic sensor system was installed in a pilot test reactor and was exposed to a constant temperature profile, with temperatures in the range of 150-500 °C for more than two years. During this period, the temperature profile was measured every three to five months and the fiber-optic temperature data were compared with data from a three-point thermocouple array and a calibrated single-point thermocouple. A very good agreement between all temperature measurements was found. The drift rates of the 24 RFBG sensor elements were determined by comparing the Bragg wavelengths at a precisely defined reference temperature near room temperature before and after the two-year deployment. They were found to be in the range of 0.0 K/a to 2.3 K/a, with an average value of 1.0 K/a. These low drift rates were achieved by a dedicated temperature treatment of the RFBGs during fabrication. Here, the demonstrated robustness, accuracy, and low drift characteristics show the potential of fiber-optic sensors for future industrial applications.

Investigations of Different Ion Intercalations on the Performance of FBG Hydrogen Sensors Based on Pt/MoO3.

α-MoO3 has been used as a hydrogen sensing material due to its excellent properties and unique crystalline layer structure. However, the low repeatability of α-MoO3 based hydrogen sensor restricts its practical application. In this paper, the effect of intercalated ion species and the amount in α-MoO3 is experimentally investigated and discussed. It is concluded that the repeatability of the sensor depends on the radius of intercalated ions and amount of ionic bonds. The optimal ion species is Na+ and the optimal amount of precursor is 1 mmol.

Strain-Independent Temperature Measurements with Surface-Glued Polarization-Maintaining Fiber Bragg Grating Sensor Elements.

A novel technique for strain and temperature decoupling with surface-glued fiber Bragg gratings (FBGs) is presented and applied for strain-independent temperature measurements in a temperature range between -30 °C and 110 °C with uncertainties below 4 °C over the entire measurement range. The influence of temperature-dependent glue-induced transversal forces on the fiber sensor could be eliminated with a sensor element consisting of two FBGs in identical polarization-maintaining fibers that were spliced perpendicular to each other. After aligning and gluing the sensor element with its optical axes parallel and perpendicular to the specimen, the averaged Bragg wavelength shifts of both FBGs were proven to be independent of the glue's influence and therefore independent of any change in the material characteristics of the glue, such as aging or creeping behavior. For the first time, this methodology enables temperature measurements with surface-attached bare FBGs independently of arbitrary longitudinal and glue-induced strains. This is of great value for all applications that rely on a fully glued sensor design, e.g., in applications with high electromagnetic fields, on rotating parts, or in vacuum for space applications.

Iterative matrix algorithm for high precision temperature and force decoupling in multi-parameter FBG sensing.

A new iterative matrix algorithm has been applied to improve the precision of temperature and force decoupling in multi-parameter FBG sensing. For the first time, this evaluation technique allows the integration of nonlinearities in the sensor's temperature characteristic and the temperature dependence of the sensor's force sensitivity. Applied to a sensor cable consisting of two FBGs in fibers with 80 µm and 125 µm cladding diameter installed in a 7 m-long coiled PEEK capillary, this technique significantly reduced the uncertainties in friction-compensated temperature measurements. In the presence of high friction-induced forces of up to 1.6 N the uncertainties in temperature evaluation were reduced from several degrees Celsius if using a standard linear matrix approach to less than 0.5°C if using the iterative matrix approach in an extended temperature range between -35°C and 125°C.

Strain Measurement in Aluminium Alloy during the Solidification Process Using Embedded Fibre Bragg Gratings.

In recent years, the observation of the behaviour of components during the production process and over their life cycle is of increasing importance. Structural health monitoring, for example of carbon composites, is state-of-the-art research. The usage of Fibre Bragg Gratings (FBGs) in this field is of major advantage. Another possible area of application is in foundries. The internal state of melts during the solidification process is of particular interest. By using embedded FBGs, temperature and stress can be monitored during the process. In this work, FBGs were embedded in aluminium alloys in order to observe the occurring strain. Two different FBG positions were chosen in the mould in order to compare its dependence. It was shown that FBGs can withstand the solidification process, although a compression in the range of one percent was measured, which is in agreement with the literature value. Furthermore, different lengths of the gratings were applied, and it was shown that shorter gratings result in more accurate measurements. The obtained results prove that FBGs are applicable as sensors for temperatures up to 740 °C.

Evidence for a motor somatotopy in the cerebellar dentate nucleus--an FMRI study in humans.

Previous anatomical studies in monkeys have shown that forelimb motor representation is located caudal to hindlimb representation within the dorso-rostral dentate nucleus. Here we investigate human dentate nucleus motor somatotopy by means of ultra-highfield (7 T) functional magnetic brain imaging (fMRI). Twenty five young healthy males participated in the study. Simple finger and foot movement tasks were performed to identify dentate nucleus motor areas. Recently developed normalization procedures for group analyses were used for the cerebellar cortex and the cerebellar dentate nucleus. Cortical activations were in good accordance with the known somatotopy of the human cerebellar cortex. Dentate nucleus activations following motor tasks were found in particular in the ipsilateral dorso-rostral nucleus. Activations were also present in other parts of the nucleus including the contralateral side, and there was some overlap between the body part representations. Within the ipsilateral dorso-rostral dentate, finger activations were located caudally compared to foot movement-related activations in fMRI group analysis. Likewise, the centre of gravity (COG) for the finger activation was more caudal than the COG of the foot activation across participants. A multivariate analysis of variance (MANOVA) on the x, y, and z coordinates of the COG indicated that this difference was significant (P = 0.043). These results indicate that in humans, the lower and upper limbs are arranged rostro-caudally in the dorsal aspect of the dentate nucleus, which is consistent with studies in non-human primates.